Self-assembly of mesoscopically ordered chromatic polydiacetylene/silica nanocomposites.

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    • Subject Terms:
      POLYMERS; SILICA; NANOPARTICLES; MOLECULAR self-assembly
    • Abstract:
      Focuses on a study on the self-assembly of conjugated polymer/silica nanocomposite films with hexagonal, cubic or lamellar mesoscopic order using polymerizable amphiphilic diacetylene molecules as both structure-directing agents and monomers. Influence of the choice of surfactant on the resultant mesostructure; Dependence of the polymerization of the surfactant upon the topological alignment of diacetylenic units with the supermolecular assembly.